Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau; Cory B. Cluff; Hannah R. Babbini; Dominic C. Babbini; Gary S. Nichol; Stephanie K Hurst

doi:10.1016/j.poly.2016.03.027

Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau, Cory B. Cluff, Hannah R. Babbini, Dominic C. Babbini, Gary S. Nichol, Stephanie K Hurst

Chemistry and Biochemistry

Research output: Contribution to journal › Article

1 Scopus citations

Abstract

The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd₃Tr₂]²⁺ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

Original language	English (US)
Pages (from-to)	443-450
Number of pages	8
Journal	Polyhedron
Volume	114
DOIs	https://doi.org/10.1016/j.poly.2016.03.027
State	Published - Aug 16 2016

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Keywords

Nitrile
Pyridine
Sandwich
Tripalladium
Tropylium

ASJC Scopus subject areas

Inorganic Chemistry
Materials Chemistry
Physical and Theoretical Chemistry

Cite this

Charbonneau, J. C., Cluff, C. B., Babbini, H. R., Babbini, D. C., Nichol, G. S., & Hurst, S. K. (2016). Tripalladium(0) sandwich complexes with nitrogen based ligands. Polyhedron, 114, 443-450. https://doi.org/10.1016/j.poly.2016.03.027

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abstract = "The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.",

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AU - Charbonneau, John C.

AU - Cluff, Cory B.

AU - Babbini, Hannah R.

AU - Babbini, Dominic C.

AU - Nichol, Gary S.

AU - Hurst, Stephanie K

PY - 2016/8/16

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N2 - The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

AB - The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

KW - Nitrile

KW - Pyridine

KW - Sandwich

KW - Tripalladium

KW - Tropylium

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10.1016/j.poly.2016.03.027