Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau, Cory B. Cluff, Hannah R. Babbini, Dominic C. Babbini, Gary S. Nichol, Stephanie K Hurst

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

Original languageEnglish (US)
Pages (from-to)443-450
Number of pages8
JournalPolyhedron
Volume114
DOIs
StatePublished - Aug 16 2016

Fingerprint

Nitrogen
Ligands
nitrogen
ligands
X ray crystallography
Microanalysis
synthesis
microanalysis
Nuclear magnetic resonance spectroscopy
crystallography
Single crystals
nuclear magnetic resonance
nuclei
single crystals
spectroscopy
x rays

Keywords

  • Nitrile
  • Pyridine
  • Sandwich
  • Tripalladium
  • Tropylium

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Materials Chemistry
  • Physical and Theoretical Chemistry

Cite this

Charbonneau, J. C., Cluff, C. B., Babbini, H. R., Babbini, D. C., Nichol, G. S., & Hurst, S. K. (2016). Tripalladium(0) sandwich complexes with nitrogen based ligands. Polyhedron, 114, 443-450. https://doi.org/10.1016/j.poly.2016.03.027

Tripalladium(0) sandwich complexes with nitrogen based ligands. / Charbonneau, John C.; Cluff, Cory B.; Babbini, Hannah R.; Babbini, Dominic C.; Nichol, Gary S.; Hurst, Stephanie K.

In: Polyhedron, Vol. 114, 16.08.2016, p. 443-450.

Research output: Contribution to journalArticle

Charbonneau, JC, Cluff, CB, Babbini, HR, Babbini, DC, Nichol, GS & Hurst, SK 2016, 'Tripalladium(0) sandwich complexes with nitrogen based ligands', Polyhedron, vol. 114, pp. 443-450. https://doi.org/10.1016/j.poly.2016.03.027
Charbonneau JC, Cluff CB, Babbini HR, Babbini DC, Nichol GS, Hurst SK. Tripalladium(0) sandwich complexes with nitrogen based ligands. Polyhedron. 2016 Aug 16;114:443-450. https://doi.org/10.1016/j.poly.2016.03.027
Charbonneau, John C. ; Cluff, Cory B. ; Babbini, Hannah R. ; Babbini, Dominic C. ; Nichol, Gary S. ; Hurst, Stephanie K. / Tripalladium(0) sandwich complexes with nitrogen based ligands. In: Polyhedron. 2016 ; Vol. 114. pp. 443-450.
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