@article{1a4f3fd5a4be45aca11506c7d10d9b2c,
title = "Tripalladium(0) sandwich complexes with nitrogen based ligands",
abstract = "The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.",
keywords = "Nitrile, Pyridine, Sandwich, Tripalladium, Tropylium",
author = "Charbonneau, {John C.} and Cluff, {Cory B.} and Babbini, {Hannah R.} and Babbini, {Dominic C.} and Nichol, {Gary S.} and Hurst, {Stephanie K.}",
note = "Funding Information: We wish to thank Northern Arizona University and the College of Engineering, Forestry and Natural Sciences for startup funding. We thank the Research Corporation for Science Advancement for their support through the Cottrell College Science Award (ID 10600). We also thank and the American Chemical Society Petroleum Research Fund (ACS-PRF Grant # 51546-UR3 ). Crystallographic data for 1b was collected by Professor Bill Clegg and Dr. Ross W. Harrington of Newcastle University. The X-ray diffractometer for 2 , 4 and 5 was purchased with funds from NSF grant CHE-9610374 . We wish to extend our thanks to the 2013 American Crystallographic Association Summer Course in Chemical Crystallography and to Prof. Alan Balch for insightful discussions. S.K.H. personally wishes to thank the many undergraduate students who worked on this challenging project over many years. Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd. All rights reserved.",
year = "2016",
month = aug,
day = "16",
doi = "10.1016/j.poly.2016.03.027",
language = "English (US)",
volume = "114",
pages = "443--450",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",
}