Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau; Cory B. Cluff; Hannah R. Babbini; Dominic C. Babbini; Gary S. Nichol; Stephanie K Hurst

doi:10.1016/j.poly.2016.03.027

Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau, Cory B. Cluff, Hannah R. Babbini, Dominic C. Babbini, Gary S. Nichol, Stephanie K Hurst

Chemistry and Biochemistry

Research output: Contribution to journal › Article

1 Scopus citations

Abstract

The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd₃Tr₂]²⁺ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

Original language	English (US)
Pages (from-to)	443-450
Number of pages	8
Journal	Polyhedron
Volume	114
DOIs	https://doi.org/10.1016/j.poly.2016.03.027
State	Published - Aug 16 2016

Keywords

Nitrile
Pyridine
Sandwich
Tripalladium
Tropylium

ASJC Scopus subject areas

Inorganic Chemistry
Materials Chemistry
Physical and Theoretical Chemistry

Access to Document

10.1016/j.poly.2016.03.027

Fingerprint Dive into the research topics of 'Tripalladium(0) sandwich complexes with nitrogen based ligands'. Together they form a unique fingerprint.

Cite this

Charbonneau, J. C., Cluff, C. B., Babbini, H. R., Babbini, D. C., Nichol, G. S., & Hurst, S. K. (2016). Tripalladium(0) sandwich complexes with nitrogen based ligands. Polyhedron, 114, 443-450. https://doi.org/10.1016/j.poly.2016.03.027

@article{1a4f3fd5a4be45aca11506c7d10d9b2c,

title = "Tripalladium(0) sandwich complexes with nitrogen based ligands",

abstract = "The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.",

keywords = "Nitrile, Pyridine, Sandwich, Tripalladium, Tropylium",

author = "Charbonneau, {John C.} and Cluff, {Cory B.} and Babbini, {Hannah R.} and Babbini, {Dominic C.} and Nichol, {Gary S.} and Hurst, {Stephanie K}",

year = "2016",

month = aug,

day = "16",

doi = "10.1016/j.poly.2016.03.027",

language = "English (US)",

volume = "114",

pages = "443--450",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Tripalladium(0) sandwich complexes with nitrogen based ligands

AU - Charbonneau, John C.

AU - Cluff, Cory B.

AU - Babbini, Hannah R.

AU - Babbini, Dominic C.

AU - Nichol, Gary S.

AU - Hurst, Stephanie K

PY - 2016/8/16

Y1 - 2016/8/16

N2 - The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

AB - The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

KW - Nitrile

KW - Pyridine

KW - Sandwich

KW - Tripalladium

KW - Tropylium

UR - http://www.scopus.com/inward/record.url?scp=84974698226&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84974698226&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2016.03.027

DO - 10.1016/j.poly.2016.03.027

M3 - Article

AN - SCOPUS:84974698226

VL - 114

SP - 443

EP - 450

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -