Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau, Cory B. Cluff, Hannah R. Babbini, Dominic C. Babbini, Gary S. Nichol, Stephanie K Hurst

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

Original languageEnglish (US)
Pages (from-to)443-450
Number of pages8
JournalPolyhedron
Volume114
DOIs
StatePublished - Aug 16 2016

Keywords

  • Nitrile
  • Pyridine
  • Sandwich
  • Tripalladium
  • Tropylium

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Materials Chemistry
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Tripalladium(0) sandwich complexes with nitrogen based ligands'. Together they form a unique fingerprint.

  • Cite this

    Charbonneau, J. C., Cluff, C. B., Babbini, H. R., Babbini, D. C., Nichol, G. S., & Hurst, S. K. (2016). Tripalladium(0) sandwich complexes with nitrogen based ligands. Polyhedron, 114, 443-450. https://doi.org/10.1016/j.poly.2016.03.027