Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges

Stephanie K. Hurst; Tong Ren

doi:10.1016/S0022-328X(02)01809-0

Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges

Stephanie K. Hurst, Tong Ren

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The reactions between Ru₂(ap)₄Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru₂(ap)₄(C≡C)₂] C₆H₃-5-C≡CH (5) and 1-[Ru₂(ap)₄(C≡C)]C₆H₃ -3,5-(C≡CH)₂ (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru₂(ap)₄ units in these complexes.

Original language	English (US)
Pages (from-to)	1-5
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	660
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(02)01809-0
State	Published - Oct 7 2002
Externally published	Yes

Keywords

2-anilinopyridinate
Acetylide
Diruthenium
Electrochemistry
Paramagnetism

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(02)01809-0

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title = "Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges",

abstract = "The reactions between Ru2(ap)4Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru2(ap)4(C≡C)2] C6H3-5-C≡CH (5) and 1-[Ru2(ap)4(C≡C)]C6H3 -3,5-(C≡CH)2 (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru2(ap)4 units in these complexes.",

keywords = "2-anilinopyridinate, Acetylide, Diruthenium, Electrochemistry, Paramagnetism",

author = "Hurst, {Stephanie K.} and Tong Ren",

note = "Funding Information: We thank both the University of Miami and Petroleum Research Fund/ACS (36595-AC3) for the financial support, and Dr G. Zou for earlier exploratory work on the synthesis of compound 3 .",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges

AU - Hurst, Stephanie K.

AU - Ren, Tong

N1 - Funding Information: We thank both the University of Miami and Petroleum Research Fund/ACS (36595-AC3) for the financial support, and Dr G. Zou for earlier exploratory work on the synthesis of compound 3 .

PY - 2002/10/7

Y1 - 2002/10/7

N2 - The reactions between Ru2(ap)4Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru2(ap)4(C≡C)2] C6H3-5-C≡CH (5) and 1-[Ru2(ap)4(C≡C)]C6H3 -3,5-(C≡CH)2 (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru2(ap)4 units in these complexes.

AB - The reactions between Ru2(ap)4Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru2(ap)4(C≡C)2] C6H3-5-C≡CH (5) and 1-[Ru2(ap)4(C≡C)]C6H3 -3,5-(C≡CH)2 (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru2(ap)4 units in these complexes.

KW - 2-anilinopyridinate

KW - Acetylide

KW - Diruthenium

KW - Electrochemistry

KW - Paramagnetism

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DO - 10.1016/S0022-328X(02)01809-0

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VL - 660

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

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Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges

Abstract

Keywords

ASJC Scopus subject areas

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