Abstract
The reactions between Ru2(ap)4Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru2(ap)4(C≡C)2] C6H3-5-C≡CH (5) and 1-[Ru2(ap)4(C≡C)]C6H3 -3,5-(C≡CH)2 (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru2(ap)4 units in these complexes.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1-5 |
| Number of pages | 5 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 660 |
| Issue number | 1 |
| DOIs | |
| State | Published - Oct 7 2002 |
| Externally published | Yes |
Fingerprint
Keywords
- 2-anilinopyridinate
- Acetylide
- Diruthenium
- Electrochemistry
- Paramagnetism
ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges. / Hurst, Stephanie K; Ren, Tong.
In: Journal of Organometallic Chemistry, Vol. 660, No. 1, 07.10.2002, p. 1-5.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis, characterization and electrochemistry of diruthenium complexes linked by aryl acetylide bridges
AU - Hurst, Stephanie K
AU - Ren, Tong
PY - 2002/10/7
Y1 - 2002/10/7
N2 - The reactions between Ru2(ap)4Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru2(ap)4(C≡C)2] C6H3-5-C≡CH (5) and 1-[Ru2(ap)4(C≡C)]C6H3 -3,5-(C≡CH)2 (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru2(ap)4 units in these complexes.
AB - The reactions between Ru2(ap)4Cl and the appropriate lithiated aryl acetylene resulted in the complexes (4), 1,3-[Ru2(ap)4(C≡C)2] C6H3-5-C≡CH (5) and 1-[Ru2(ap)4(C≡C)]C6H3 -3,5-(C≡CH)2 (6), where ap is 2-anilinopyridinate. The spectroscopic and electrochemical properties of the new complexes have been assessed. Complexes 3, 4 and 6 display two-electron oxidation and reductions, implying the absence of any significant electronic interaction between the two Ru2(ap)4 units in these complexes.
KW - 2-anilinopyridinate
KW - Acetylide
KW - Diruthenium
KW - Electrochemistry
KW - Paramagnetism
UR - http://www.scopus.com/inward/record.url?scp=0037037368&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037037368&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(02)01809-0
DO - 10.1016/S0022-328X(02)01809-0
M3 - Article
AN - SCOPUS:0037037368
VL - 660
SP - 1
EP - 5
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1
ER -