Static secondary ionization mass spectrometry detection of cyclohexylamine on soil surfaces exposed to laboratory air

Gary S. Groenewold, J. C. Ingram, A. K. Gianotto, A. D. Appelhans, J. E. Delmore

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

Cyclohexylamine (CHA) is a common indoor air contaminant, which rapidly adsorbs to aluminosilicate soil samples. Static secondary ion mass spectrometry was used to study soil samples exposed to both CHA and CHA-d11, and the results showed (1) abundant [M + H]+ and fragment ions that originated from CHA, (2) an initial concentration of CHA equivalent to approximately 0.2 monolayer, and (3) a possible exchange reaction where excess CHA-d11 displaces CHA originally adsorbed to the surface. CHA was not removed from the surface by prolonged exposure to vacuum conditions (5 × 10-7 torr), which indicates that CHA strongly adsorbs to aluminosilicate surfaces and should be expected as an endogenous surface contaminant where the chemical is used as a corrosion inhibitor. (J Am Soc Mass Spectrom 1996, 7, 168-172).

Original languageEnglish (US)
Pages (from-to)168-172
Number of pages5
JournalJournal of the American Society for Mass Spectrometry
Volume7
Issue number2
DOIs
StatePublished - Feb 1996

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ASJC Scopus subject areas

  • Structural Biology
  • Spectroscopy

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