Abstract
The direct combination reaction of tropylium tetrafluoroborate with a range of mono- and bi-dentate phosphines in chlorinated solvents leads to the formation of a series of cycloheptatriene-phosphonium derivatives in excellent yields. Multi-nuclear NMR and single-crystal X-ray diffraction studies confirm the addition of the tropylium ligand to the phosphorous centre to form cycloheptatriene derivatives.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 6319-6322 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 56 |
| Issue number | 46 |
| DOIs | |
| State | Published - Nov 18 2015 |
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Keywords
- Cycloheptatriene
- Dppe
- Dppf
- Dppp
- Phosphonium
- Tropylium
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
Cite this
Rapid one-pot synthesis of cycloheptatriene-phosphonium derivatives. / Kruse, Samantha M.; Hurst, Stephanie K.
In: Tetrahedron Letters, Vol. 56, No. 46, 18.11.2015, p. 6319-6322.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rapid one-pot synthesis of cycloheptatriene-phosphonium derivatives
AU - Kruse, Samantha M.
AU - Hurst, Stephanie K
PY - 2015/11/18
Y1 - 2015/11/18
N2 - The direct combination reaction of tropylium tetrafluoroborate with a range of mono- and bi-dentate phosphines in chlorinated solvents leads to the formation of a series of cycloheptatriene-phosphonium derivatives in excellent yields. Multi-nuclear NMR and single-crystal X-ray diffraction studies confirm the addition of the tropylium ligand to the phosphorous centre to form cycloheptatriene derivatives.
AB - The direct combination reaction of tropylium tetrafluoroborate with a range of mono- and bi-dentate phosphines in chlorinated solvents leads to the formation of a series of cycloheptatriene-phosphonium derivatives in excellent yields. Multi-nuclear NMR and single-crystal X-ray diffraction studies confirm the addition of the tropylium ligand to the phosphorous centre to form cycloheptatriene derivatives.
KW - Cycloheptatriene
KW - Dppe
KW - Dppf
KW - Dppp
KW - Phosphonium
KW - Tropylium
UR - http://www.scopus.com/inward/record.url?scp=84946102661&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84946102661&partnerID=8YFLogxK
U2 - 10.1016/j.tetlet.2015.06.097
DO - 10.1016/j.tetlet.2015.06.097
M3 - Article
AN - SCOPUS:84946102661
VL - 56
SP - 6319
EP - 6322
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 46
ER -