Organometallic complexes for nonlinear optics

Part 23. Quadratic and cubic hyperpolarizabilities of acetylide and vinylidene complexes derived from protected and free formylphenylacetylenes

Stephanie K Hurst, Nigel T. Lucas, Marie P. Cifuentes, Mark G. Humphrey, Marek Samoc, Barry Luther-Davies, Inge Asselberghs, Roel Van Boxel, André Persoons

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

The acetylenes 4-HCCC6H4R [R=CH{OC(O)Me}2 (1), CHO(CH2)3O (2)], ruthenium complexes [Ru(4-CCC6H4R)(PPh3)2(η-C 5H5)] [R=CH{OC(O)Me}2 (3), CHO (4)], [Ru(n-C=CHC6H4R)Cl(dppm)2]PF6 [n=4, R=CHO(CH2)3O (7); R=CHO, n=3 (11), 2 (15)], and [Ru(n-CCC6H4R)Cl(dppm)2] [n=4, R=CHO(CH2)3O (8); n=3, R=CHO (12)], and gold complexes [Au(n-CCC6H4R)(L)] [n=4, R=CHO, L=PPh3 (5), PMe3 (6); n=4, R=CHO(CH2)3O, L=PPh3 (9), PMe3 (10); n=3, R=CHO, L=PPh3 (13), PMe3 (14)] have been prepared, and 9 characterized by a single crystal X-ray diffraction study. Electrochemical data for the ruthenium complexes reveal reversible or quasi-reversible (alkynyl complexes) or irreversible (vinylidene complexes) processes assigned to the RuII/III couple; the effect on E1/2 values of the various structural modifications across 3, 4, 7, 8, 11, 12 and 15 are discussed. The molecular quadratic and cubic optical nonlinearities of 1-15 have been determined by the hyper-Rayleigh scattering technique at 1064 nm and the Z-scan technique at 800 nm, respectively; β values increase on increasing the acceptor strength, proceeding from 3-acceptor-substituted to 4-acceptor-substituted arylalkynyl ligand, and an increasing phosphine donor strength, whereas γ values increase on increasing the number of phosphine aryl groups (i.e. increasing delocalization) proceeding from PMe3 to PPh3-containing complex.

Original languageEnglish (US)
Pages (from-to)114-124
Number of pages11
JournalJournal of Organometallic Chemistry
Volume633
Issue number1-2
DOIs
StatePublished - Aug 10 2001
Externally publishedYes

Fingerprint

phosphine
Nonlinear optics
Ruthenium
nonlinear optics
Organometallics
vinylidene
Rayleigh scattering
Alkynes
Acetylene
phosphines
X-Ray Diffraction
Gold
ruthenium
Ligands
Single crystals
methylidyne
X ray diffraction
acetylene
nonlinearity
gold

Keywords

  • Acetylide
  • Electrochemistry
  • Gold
  • Hyperpolarizability
  • Ruthenium
  • Vinylidene
  • X-ray structure

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Organometallic complexes for nonlinear optics : Part 23. Quadratic and cubic hyperpolarizabilities of acetylide and vinylidene complexes derived from protected and free formylphenylacetylenes. / Hurst, Stephanie K; Lucas, Nigel T.; Cifuentes, Marie P.; Humphrey, Mark G.; Samoc, Marek; Luther-Davies, Barry; Asselberghs, Inge; Van Boxel, Roel; Persoons, André.

In: Journal of Organometallic Chemistry, Vol. 633, No. 1-2, 10.08.2001, p. 114-124.

Research output: Contribution to journalArticle

Hurst, Stephanie K ; Lucas, Nigel T. ; Cifuentes, Marie P. ; Humphrey, Mark G. ; Samoc, Marek ; Luther-Davies, Barry ; Asselberghs, Inge ; Van Boxel, Roel ; Persoons, André. / Organometallic complexes for nonlinear optics : Part 23. Quadratic and cubic hyperpolarizabilities of acetylide and vinylidene complexes derived from protected and free formylphenylacetylenes. In: Journal of Organometallic Chemistry. 2001 ; Vol. 633, No. 1-2. pp. 114-124.
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abstract = "The acetylenes 4-HCCC6H4R [R=CH{OC(O)Me}2 (1), CHO(CH2)3O (2)], ruthenium complexes [Ru(4-CCC6H4R)(PPh3)2(η-C 5H5)] [R=CH{OC(O)Me}2 (3), CHO (4)], [Ru(n-C=CHC6H4R)Cl(dppm)2]PF6 [n=4, R=CHO(CH2)3O (7); R=CHO, n=3 (11), 2 (15)], and [Ru(n-CCC6H4R)Cl(dppm)2] [n=4, R=CHO(CH2)3O (8); n=3, R=CHO (12)], and gold complexes [Au(n-CCC6H4R)(L)] [n=4, R=CHO, L=PPh3 (5), PMe3 (6); n=4, R=CHO(CH2)3O, L=PPh3 (9), PMe3 (10); n=3, R=CHO, L=PPh3 (13), PMe3 (14)] have been prepared, and 9 characterized by a single crystal X-ray diffraction study. Electrochemical data for the ruthenium complexes reveal reversible or quasi-reversible (alkynyl complexes) or irreversible (vinylidene complexes) processes assigned to the RuII/III couple; the effect on E1/2 values of the various structural modifications across 3, 4, 7, 8, 11, 12 and 15 are discussed. The molecular quadratic and cubic optical nonlinearities of 1-15 have been determined by the hyper-Rayleigh scattering technique at 1064 nm and the Z-scan technique at 800 nm, respectively; β values increase on increasing the acceptor strength, proceeding from 3-acceptor-substituted to 4-acceptor-substituted arylalkynyl ligand, and an increasing phosphine donor strength, whereas γ values increase on increasing the number of phosphine aryl groups (i.e. increasing delocalization) proceeding from PMe3 to PPh3-containing complex.",
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AU - Hurst, Stephanie K

AU - Lucas, Nigel T.

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Samoc, Marek

AU - Luther-Davies, Barry

AU - Asselberghs, Inge

AU - Van Boxel, Roel

AU - Persoons, André

PY - 2001/8/10

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N2 - The acetylenes 4-HCCC6H4R [R=CH{OC(O)Me}2 (1), CHO(CH2)3O (2)], ruthenium complexes [Ru(4-CCC6H4R)(PPh3)2(η-C 5H5)] [R=CH{OC(O)Me}2 (3), CHO (4)], [Ru(n-C=CHC6H4R)Cl(dppm)2]PF6 [n=4, R=CHO(CH2)3O (7); R=CHO, n=3 (11), 2 (15)], and [Ru(n-CCC6H4R)Cl(dppm)2] [n=4, R=CHO(CH2)3O (8); n=3, R=CHO (12)], and gold complexes [Au(n-CCC6H4R)(L)] [n=4, R=CHO, L=PPh3 (5), PMe3 (6); n=4, R=CHO(CH2)3O, L=PPh3 (9), PMe3 (10); n=3, R=CHO, L=PPh3 (13), PMe3 (14)] have been prepared, and 9 characterized by a single crystal X-ray diffraction study. Electrochemical data for the ruthenium complexes reveal reversible or quasi-reversible (alkynyl complexes) or irreversible (vinylidene complexes) processes assigned to the RuII/III couple; the effect on E1/2 values of the various structural modifications across 3, 4, 7, 8, 11, 12 and 15 are discussed. The molecular quadratic and cubic optical nonlinearities of 1-15 have been determined by the hyper-Rayleigh scattering technique at 1064 nm and the Z-scan technique at 800 nm, respectively; β values increase on increasing the acceptor strength, proceeding from 3-acceptor-substituted to 4-acceptor-substituted arylalkynyl ligand, and an increasing phosphine donor strength, whereas γ values increase on increasing the number of phosphine aryl groups (i.e. increasing delocalization) proceeding from PMe3 to PPh3-containing complex.

AB - The acetylenes 4-HCCC6H4R [R=CH{OC(O)Me}2 (1), CHO(CH2)3O (2)], ruthenium complexes [Ru(4-CCC6H4R)(PPh3)2(η-C 5H5)] [R=CH{OC(O)Me}2 (3), CHO (4)], [Ru(n-C=CHC6H4R)Cl(dppm)2]PF6 [n=4, R=CHO(CH2)3O (7); R=CHO, n=3 (11), 2 (15)], and [Ru(n-CCC6H4R)Cl(dppm)2] [n=4, R=CHO(CH2)3O (8); n=3, R=CHO (12)], and gold complexes [Au(n-CCC6H4R)(L)] [n=4, R=CHO, L=PPh3 (5), PMe3 (6); n=4, R=CHO(CH2)3O, L=PPh3 (9), PMe3 (10); n=3, R=CHO, L=PPh3 (13), PMe3 (14)] have been prepared, and 9 characterized by a single crystal X-ray diffraction study. Electrochemical data for the ruthenium complexes reveal reversible or quasi-reversible (alkynyl complexes) or irreversible (vinylidene complexes) processes assigned to the RuII/III couple; the effect on E1/2 values of the various structural modifications across 3, 4, 7, 8, 11, 12 and 15 are discussed. The molecular quadratic and cubic optical nonlinearities of 1-15 have been determined by the hyper-Rayleigh scattering technique at 1064 nm and the Z-scan technique at 800 nm, respectively; β values increase on increasing the acceptor strength, proceeding from 3-acceptor-substituted to 4-acceptor-substituted arylalkynyl ligand, and an increasing phosphine donor strength, whereas γ values increase on increasing the number of phosphine aryl groups (i.e. increasing delocalization) proceeding from PMe3 to PPh3-containing complex.

KW - Acetylide

KW - Electrochemistry

KW - Gold

KW - Hyperpolarizability

KW - Ruthenium

KW - Vinylidene

KW - X-ray structure

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