Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Stephanie K Hurst, Mark G. Humphrey, Takashi Isoshima, Kurt Wostyn, Inge Asselberghs, Koen Clays, André Persoons, Marek Samoc, Barry Luther-Davies

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\800 and two-photon absorption cross-sections σ2 increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ(3) were also found to be large and scaling with the number of metal atoms.

Original languageEnglish (US)
Pages (from-to)2024-2026
Number of pages3
JournalOrganometallics
Volume21
Issue number10
DOIs
StatePublished - May 13 2002
Externally publishedYes

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Nonlinear optics
nonlinear optics
Organometallics
absorption cross sections
Photons
Metals
nonlinearity
analogs
magnetic permeability
scaling
Atoms
photons
metals
atoms

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes. / Hurst, Stephanie K; Humphrey, Mark G.; Isoshima, Takashi; Wostyn, Kurt; Asselberghs, Inge; Clays, Koen; Persoons, André; Samoc, Marek; Luther-Davies, Barry.

In: Organometallics, Vol. 21, No. 10, 13.05.2002, p. 2024-2026.

Research output: Contribution to journalArticle

Hurst, SK, Humphrey, MG, Isoshima, T, Wostyn, K, Asselberghs, I, Clays, K, Persoons, A, Samoc, M & Luther-Davies, B 2002, 'Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes', Organometallics, vol. 21, no. 10, pp. 2024-2026. https://doi.org/10.1021/om020008c
Hurst, Stephanie K ; Humphrey, Mark G. ; Isoshima, Takashi ; Wostyn, Kurt ; Asselberghs, Inge ; Clays, Koen ; Persoons, André ; Samoc, Marek ; Luther-Davies, Barry. / Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes. In: Organometallics. 2002 ; Vol. 21, No. 10. pp. 2024-2026.
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