New trimetallic sandwich complexes of platinum(0) and palladium(0)

Dominic C. Babbini, Kyle J. Cluff, Nathan B. Fisher, John C. Charbonneau, Gary S. Nichol, Stephanie K. Hurst

Research output: Contribution to journalShort survey

11 Scopus citations

Abstract

The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2] 2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium-platinum sandwich complexes could also be formed [PdnPt3-nTr 2X3][Y] (X = Cl, Br and I, Y = NBu4 + or PBu4 +).

Original languageEnglish (US)
Pages (from-to)217-221
Number of pages5
JournalJournal of Organometallic Chemistry
Volume713
DOIs
StatePublished - Aug 15 2012

Keywords

  • Organometallic
  • Palladium
  • Platinum
  • Tropylium

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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