New trimetallic sandwich complexes of platinum(0) and palladium(0)

Dominic C. Babbini, Kyle J. Cluff, Nathan B. Fisher, John C. Charbonneau, Gary S. Nichol, Stephanie K Hurst

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt 3Tr 2] 2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium-platinum sandwich complexes could also be formed [Pd nPt 3-nTr 2X 3][Y] (X = Cl, Br and I, Y = NBu 4 + or PBu 4 +).

Original languageEnglish (US)
Pages (from-to)217-221
Number of pages5
JournalJournal of Organometallic Chemistry
Volume713
DOIs
StatePublished - Aug 15 2012

Fingerprint

X ray crystallography
X Ray Crystallography
Microanalysis
Palladium
Platinum
microanalysis
Nuclear magnetic resonance spectroscopy
crystallography
halides
Mass spectrometry
palladium
Mass Spectrometry
platinum
Magnetic Resonance Spectroscopy
mass spectroscopy
Metals
Ligands
nuclear magnetic resonance
ligands
nuclei

Keywords

  • Organometallic
  • Palladium
  • Platinum
  • Tropylium

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

Cite this

New trimetallic sandwich complexes of platinum(0) and palladium(0). / Babbini, Dominic C.; Cluff, Kyle J.; Fisher, Nathan B.; Charbonneau, John C.; Nichol, Gary S.; Hurst, Stephanie K.

In: Journal of Organometallic Chemistry, Vol. 713, 15.08.2012, p. 217-221.

Research output: Contribution to journalArticle

Babbini, Dominic C. ; Cluff, Kyle J. ; Fisher, Nathan B. ; Charbonneau, John C. ; Nichol, Gary S. ; Hurst, Stephanie K. / New trimetallic sandwich complexes of platinum(0) and palladium(0). In: Journal of Organometallic Chemistry. 2012 ; Vol. 713. pp. 217-221.
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