Monomers and polymers of tripalladium(0) ditropylium halides

Frank L. Mulligan, Dominic C. Babbini, Isaac R. Davis, Stephanie K. Hurst, Gary S. Nichol

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27 Scopus citations

Abstract

The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd 3Tr 2] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd 3Tr 2X 2] (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.

Original languageEnglish (US)
Pages (from-to)2708-2710
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number7
DOIs
StatePublished - Apr 17 2009

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Mulligan, F. L., Babbini, D. C., Davis, I. R., Hurst, S. K., & Nichol, G. S. (2009). Monomers and polymers of tripalladium(0) ditropylium halides. Inorganic Chemistry, 48(7), 2708-2710. https://doi.org/10.1021/ic8014578