Monomers and polymers of tripalladium(0) ditropylium halides

Frank L. Mulligan, Dominic C. Babbini, Isaac R. Davis, Stephanie K Hurst, Gary S. Nichol

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd 3Tr 2] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd 3Tr 2X 2] (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.

Original languageEnglish (US)
Pages (from-to)2708-2710
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number7
DOIs
StatePublished - 2009

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halides
Polymers
monomers
Monomers
Ligands
Inorganic polymers
ligands
X ray crystallography
polymers
microanalysis
Nuclear magnetic resonance spectroscopy
crystallography
Mass spectrometry
mass spectroscopy
nuclear magnetic resonance
synthesis
products
spectroscopy
x rays

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Mulligan, F. L., Babbini, D. C., Davis, I. R., Hurst, S. K., & Nichol, G. S. (2009). Monomers and polymers of tripalladium(0) ditropylium halides. Inorganic Chemistry, 48(7), 2708-2710. https://doi.org/10.1021/ic8014578

Monomers and polymers of tripalladium(0) ditropylium halides. / Mulligan, Frank L.; Babbini, Dominic C.; Davis, Isaac R.; Hurst, Stephanie K; Nichol, Gary S.

In: Inorganic Chemistry, Vol. 48, No. 7, 2009, p. 2708-2710.

Research output: Contribution to journalArticle

Mulligan, FL, Babbini, DC, Davis, IR, Hurst, SK & Nichol, GS 2009, 'Monomers and polymers of tripalladium(0) ditropylium halides', Inorganic Chemistry, vol. 48, no. 7, pp. 2708-2710. https://doi.org/10.1021/ic8014578
Mulligan, Frank L. ; Babbini, Dominic C. ; Davis, Isaac R. ; Hurst, Stephanie K ; Nichol, Gary S. / Monomers and polymers of tripalladium(0) ditropylium halides. In: Inorganic Chemistry. 2009 ; Vol. 48, No. 7. pp. 2708-2710.
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