Identifying outliers and assessing the accuracy of amino acid racemization measurements for geochronology: I. Age calibration curves

Matthew A. Kosnik, Darrell S Kaufman, Quan Hua

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Numerical ages derived from amino acid racemization (AAR) geochronology are typically based on calibration curves that relate the extent of AAR to the age of independently dated specimens. Here, we compare options for developing calibration curves and quantifying age uncertainties using AAR data from 481 late Holocene shells, and AMS 14C analyses of 36 shells of four molluscan taxa (Ethalia, Natica, Tellina, and Turbo) collected from shallow sediment cores from a back-reef lagoon of the central Great Barrier Reef. The four taxa differed substantially in the quality of their geochronogical results. Explicitly including data from specimens alive at the time of collection improves calibration curves, but weighting numerical ages based on their uncertainty has no effect. Calibration curve statistics do not adequately assess calibration uncertainty. The relation between ages inferred from different amino acids is recommended for identifying aberrant specimens and quantifying the uncertainty of inferred ages. For this study, the AAR ages based on two amino acids (aspartic acid and glutamic acid) exceed 200 yr or 20% of their mean inferred age in ∼15% of the specimens. Once these were removed, the mean age error (1σ) for individual specimens based on two amino acids analyzed in duplicate subsamples ranged from 53 to 142 yr for Tellina and Turbo, respectively, or about a 30% age error for these relatively young shells. This compares favorably with analytical errors estimated at 50 yr or 5%. The presence of notable outliers undetectable using data from single amino acids emphasizes the importance of analyzing multiple amino acids.

Original languageEnglish (US)
Pages (from-to)308-327
Number of pages20
JournalQuaternary Geochronology
Volume3
Issue number4
DOIs
StatePublished - Nov 2008

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racemization
outlier
geochronology
amino acid
calibration
shell
aspartic acid
accelerator mass spectrometry
barrier reef
sediment core
lagoon
reef
Holocene

Keywords

  • Age calibration curves
  • Amino acid geochronology
  • Carbon-14
  • Carbonate sediments
  • Holocene
  • Mollusca

ASJC Scopus subject areas

  • Geology
  • Earth and Planetary Sciences (miscellaneous)
  • Stratigraphy

Cite this

Identifying outliers and assessing the accuracy of amino acid racemization measurements for geochronology : I. Age calibration curves. / Kosnik, Matthew A.; Kaufman, Darrell S; Hua, Quan.

In: Quaternary Geochronology, Vol. 3, No. 4, 11.2008, p. 308-327.

Research output: Contribution to journalArticle

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