Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br2

David A. Sartori, Stephanie K Hurst, Nathan Wood, Raymond D. Larsen, Edwin H. Abbott

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The complex dibromobipyridylplatinum(II), Pt(bipy)Br2, crystallizes in the monoclinic space group C2/c with a = 17.262(5) Å, b = 9.388(2) Å, c = 7.557(2) Å, β = 113.47(2)°, and Z = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br 2. The 195Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at -1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)2 (X = Cl and I) and Pd(bipy)Br2.

Original languageEnglish (US)
Pages (from-to)995-998
Number of pages4
JournalJournal of Chemical Crystallography
Volume35
Issue number12
DOIs
StatePublished - Dec 2005
Externally publishedYes

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Copper
Nitrogen
Physical properties
physical properties
Crystal structure
Nuclear magnetic resonance
Derivatives
nitrogen
copper
nuclear magnetic resonance
crystal structure

Keywords

  • Bipy
  • Bipyridyl
  • Platinum(II) complex
  • Pt-195 NMR

ASJC Scopus subject areas

  • Spectroscopy
  • Condensed Matter Physics
  • Structural Biology

Cite this

Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br2. / Sartori, David A.; Hurst, Stephanie K; Wood, Nathan; Larsen, Raymond D.; Abbott, Edwin H.

In: Journal of Chemical Crystallography, Vol. 35, No. 12, 12.2005, p. 995-998.

Research output: Contribution to journalArticle

Sartori, David A. ; Hurst, Stephanie K ; Wood, Nathan ; Larsen, Raymond D. ; Abbott, Edwin H. / Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br2. In: Journal of Chemical Crystallography. 2005 ; Vol. 35, No. 12. pp. 995-998.
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AB - The complex dibromobipyridylplatinum(II), Pt(bipy)Br2, crystallizes in the monoclinic space group C2/c with a = 17.262(5) Å, b = 9.388(2) Å, c = 7.557(2) Å, β = 113.47(2)°, and Z = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br 2. The 195Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at -1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)2 (X = Cl and I) and Pd(bipy)Br2.

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