Characterization of 234U/238U Activity Ratios and Potential Inorganic Uranium Complexation Species in Unregulated Water Sources in the Southwest Region of the Navajo Reservation

Nicole R. Campbell, Jani C Ingram

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Extensive uranium mining occurred from the mid- to late-1900s on Navajo tribal lands in Northern Arizona, an area rich in natural uranium. In this study, water samples from unregulated sources on the Navajo Reservation were analyzed to determine elemental uranium concentration, 234U/238U activity ratios, and existing inorganic anions. These data provide a more complete understanding of uranium source and the formation of potential uranium complexes. Results of the current studies suggest that some wells on the Navajo Nation have uranium concentrations near or above the U.S. Environmental Protection Agency guideline of 30μg/l. The 234U/238U activity ratios were similar for water wells located near mining sites with ratios of 1-1.5, and for those from the control, activity ratios were observed at 2.5-4.5. Two wells were observed to have high uranium and bicarbonate content suggesting the presence of uranyl carbonate species that may increase the solubility of uranium.

Original languageEnglish (US)
Title of host publicationWater Reclamation and Sustainability
PublisherElsevier Inc.
Pages77-94
Number of pages18
ISBN (Print)9780124165762, 9780124116450
DOIs
StatePublished - Jun 5 2014

Keywords

  • Groundwater
  • Ion composition
  • Navajo
  • Uranium

ASJC Scopus subject areas

  • Chemistry(all)

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