Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)]

Frank Mulligan, Gary S. Nichol, Stephanie K Hurst

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Abstract

The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The mol-ecular dimensions are unexceptional and the Pd⋯Pd distance, at 3.8183 (12) Å, is much too long for any Pd - Pd inter-action. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number10
DOIs
StatePublished - 2007

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ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

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